Chuck (8pm, NBC) - Awesome is mistaken for a super spy by the evil Sydney Price (Angie Harmon) so Chuck must become his handler and show him the ropes. Brandon Routh ("Superman Returns") also guest stars.
24 (8pm, Fox) - Another two hours of Jack saving the world.
Antiques Roadshow (8pm, UNC-TV) - The conclusion of the Raleigh episodes. The crew visits the Museum of the Cape Fear in Fayetteville, and highlights Civil War-era weapons that were made in North Carolina. Look for items related to Martin Luther King Jr.'s 1966 visit to Durham.
How I Met Your Mother (8pm, CBS) - Marshall tries to convince Lily that a beautiful woman (Amanda Peet) kissed him. Robin learns she's the subject of a drinking game.
Life Unexpected (9pm, CW) - A great new series from The CW about a young girl in foster care who tracks down her birth parents hoping she can get emancipated and live on her own.
Big Bang Theory (9:30pm, CBS) - When Leonard and Sheldon's apartment is robbed, they create an elaborate security system.
Brooke Cain isn't always proud of the number of hours she logs in front of the TV, but her loss of brain cells can be your gain. From reality shows to sitcoms to the more serious stuff, Brooke keeps her DVR smoking so that she can help keep you in the know. Brooke also tweets for Happiness is a Warm TV (you can follow