Chuck (8pm, NBC) - Awesome is mistaken for a super spy by the evil Sydney Price (Angie Harmon) so Chuck must become his handler and show him the ropes. Brandon Routh ("Superman Returns") also guest stars.
24 (8pm, Fox) - Another two hours of Jack saving the world.
Antiques Roadshow (8pm, UNC-TV) - The conclusion of the Raleigh episodes. The crew visits the Museum of the Cape Fear in Fayetteville, and highlights Civil War-era weapons that were made in North Carolina. Look for items related to Martin Luther King Jr.'s 1966 visit to Durham.
How I Met Your Mother (8pm, CBS) - Marshall tries to convince Lily that a beautiful woman (Amanda Peet) kissed him. Robin learns she's the subject of a drinking game.
Life Unexpected (9pm, CW) - A great new series from The CW about a young girl in foster care who tracks down her birth parents hoping she can get emancipated and live on her own.
Big Bang Theory (9:30pm, CBS) - When Leonard and Sheldon's apartment is robbed, they create an elaborate security system.