Moguls & Movie Stars: A History of Hollywood (8pm, Turner Classic Movies) - The first in a seven-part look at the Hollywood film industry starts with "Peepshow Pioneers," covering the years 1889-1907. Features interviews with film historians, including Leonard Maltin, and descendants of Hollywood moguls Louis B. Mayer, William Fox, Adolph Zucker, and the Warner brothers.
Chuck (8pm, NBC) - In the wake of his first fight with Sarah, Chuck embarks on a rogue mission ultimately colliding with his mother's spy handler, played by ex-James Bond Timothy Dalton (right). Dalton is on board for a multi-episode arc. Ana Gasteyer (SNL) also appears as an enigmatic Russian agent.
The Women of SNL (9pm, NBC) - A skit show featuring clips of memorable performances by the female members of SNL's cast. Featured: Tina Fey, Julia Louis-Dreyfus, Amy Poehler, Rachel Dretch, Nora Dunn, Laraine Newman, Kristin Wiig, Molly Shannon, Maya Rudolph, and Ana Gasteyer.
Gossip Girl (9pm, CW) - Blair is ill-prepared for an unexpected party guest on her birthday. Meanwhile, Serena and Nate try to put an end to Chuck and Blair's endless games. Singer Robyn performs.
Castle (10pm, ABC) - A male stripper dressed as a cop is found murdered after Beckett and Castle respond to an officer down call, and the probe focuses on the victim's life as a struggling actor.
Brooke Cain isn't always proud of the number of hours she logs in front of the TV, but her loss of brain cells can be your gain. From reality shows to sitcoms to the more serious stuff, Brooke keeps her DVR smoking so that she can help keep you in the know. Brooke also tweets for Happiness is a Warm TV (you can follow