Moguls & Movie Stars: A History of Hollywood (8pm, Turner Classic Movies) - The first in a seven-part look at the Hollywood film industry starts with "Peepshow Pioneers," covering the years 1889-1907. Features interviews with film historians, including Leonard Maltin, and descendants of Hollywood moguls Louis B. Mayer, William Fox, Adolph Zucker, and the Warner brothers.
Chuck (8pm, NBC) - In the wake of his first fight with Sarah, Chuck embarks on a rogue mission ultimately colliding with his mother's spy handler, played by ex-James Bond Timothy Dalton (right). Dalton is on board for a multi-episode arc. Ana Gasteyer (SNL) also appears as an enigmatic Russian agent.
The Women of SNL (9pm, NBC) - A skit show featuring clips of memorable performances by the female members of SNL's cast. Featured: Tina Fey, Julia Louis-Dreyfus, Amy Poehler, Rachel Dretch, Nora Dunn, Laraine Newman, Kristin Wiig, Molly Shannon, Maya Rudolph, and Ana Gasteyer.
Gossip Girl (9pm, CW) - Blair is ill-prepared for an unexpected party guest on her birthday. Meanwhile, Serena and Nate try to put an end to Chuck and Blair's endless games. Singer Robyn performs.
Castle (10pm, ABC) - A male stripper dressed as a cop is found murdered after Beckett and Castle respond to an officer down call, and the probe focuses on the victim's life as a struggling actor.