Nova: Mystery of a Masterpiece (9pm, UNC-TV) - Nova examines the work of art sleuths who tackle "cold case" art mysteries as well as the criminal market in stolen and fraudulent art. Includes a look at image analysis which reveals a portrait purchased for $20,000 to be a lost work of Leonardo da Vinci, which revalues the painting at $100 million.
Criminal Minds (9pm, CBS) - A serial rapist in Houston known as "The Piano Man" resurfaces and assaults his previous victims. Meanwhile, Prentiss deals with the trauma of rejoining the team.
Touch (9pm, Fox) - The debut of a new drama in which a blue-collar New York widower (Kiefer Sutherland) gets help from a social worker and an educator in an attempt to bond with his emotionally troubled son, whose obsession with numbers appears to enable him to predict the future. Adrienne has a review.
CSI (10pm, CBS) - Catherine (Marg Helgenberger, right) makes the painful decision to leave CSI. This is the final episode for Helgenberger, who has been on the show for 12 seasons. She hasn't ruled out returning for an occasional guest spot.
Royal Pains (10pm, USA) - Members of a rock band become ill, forcing Hank and Divya to figure out the cause, but the prescription debacle puts a strain on their working relationship.
Hot in Cleveland (10pm, TV Land) - Victoria's daughter arrives for a visit with the news that she and Melanie's son are engaged. Meanwhile, Joy's blind boyfriend thinks she's 26 and Elka prank-calls the New York Yankees third baseman.

Are You There, Chelsea? (8:30pm, NBC) - The premiere of a confusing new series about a sassy young bar worker, Chelsea Newman, and her group of twentysomething pals. The book is inspired by Chelsea Handler's book, "Are You There, Vodka? It's Me, Chelsea," but the Chelsea character is played by Laura Prepon. Adding to the confusion, Chelsea Handler, wearing a brunette wig, plays Chelsea's sister. So it's a show about Chelsea Handler starring Chelsea Handler, but Chelsea doesn't play Chelsea. Got it? Also, don't expect much.
Nova: Deadliest Volcanos (9pm, UNC-TV) - The season premiere looks at the work of scientists who are studying active volcanoes in an attempt to learn how likely they are to erupt, when eruptions might happen, and how deadly they could be.
Nova: Iceman Murder Mystery (9pm, UNC-TV) - An autopsy on the 5000-year-old remains of Otzi the Iceman, the mummified corpse recovered from a glacier in the Italian Alps in 1991, reveals details of life during the Copper Age, including people's diet and the types of diseases they dealt with.
H8R (8pm, CW) - Tonight, Kim Kardashian meets a hater. In other words, Kim Kardashian meets America.
Saved: 9/11/2001 (9pm, Animal Planet) - Tonight's episode of "Saved," a show which chronicles the stories of humans bonding with animals to cope with loss and tragedy, has a 9/11-theme. Included: a dalmation adopted by the mother of fallen firefighters and a Yorkshire terrier that helped a little girl who was traumatized by 9/11.
Nova: Making Stuff Cleaner (9pm, UNC-TV) - Part 3 of 4 of "Making Stuff" examines the science and business of clean energy. Included: a scientist who uses chicken feathers to make hydrogen-powerd cars safer, whether lithium batteries create a dependence on South America, and whether scientists can create batteries that run on molten salts.
NOVA: Mind Over Money (8pm, UNC-TV) - If you've got your mind on your money and your money on your mind, Nova can tell you why. It seems the brain actually misfires and makes us irrational when money is involved. A fascinating look at behavioral economics.
