Arrow (8pm, CW) - Laurel is targeted by the violent Chinese Triad and by ruthless mercenary China White, while Oliver is asked to take over his family's company.
World Without End (8pm, Reelz) - A miniseries based on the best selling fantasy novel by Ken Follett.
The Neighbors (8:30pm, ABC) - Marty and Debbie help Larry and Jackie's kids, Reggie Jackson and Dick Butkus, get ready for their first day of school with humans. But when an anti-bullying tactic goes awry, the Bird-Kersees grow frustrated with their neighbors' parenting advice.
Nova: Forensics on Trial (9pm, UNC-TV) - An examination of modern forensic science, which is a far cry from what's presented on crime dramas. (We're looking at you, "CSI.") Few established scientific standards, no central oversight and poor regulation of examiner shave led to many wrongful convictions.
Suburgatory (9:30pm, ABC) - In the Season 2 premiere, Tessa (Jane Levy, right) comes back to the suburbs after spending the summer with her grandmother in New York City, where she discovered her mother's musical talents.
American Horror Story: Asylum (10pm, FX) - In the second season premiere, the evils of Briarcliff Manor, a notorious insane asylum, are exposed. This is a totally separate story with different characters than we got in Season 1. Jessica Lange returns this season but doesn't play the same character.
Nashville (10pm, ABC) - Teddy's run for office requires a background check, which exposes shocking family secrets. Meanwhile, Coleman discovers that Lamar is ready to battle him, and Juliette makes a keen observation about Deacon.
Chicago Fire (10pm, NBC) - Severide is still consumed with guilt over Andy Darden's death, and his remorse is only intensified when he learns that Darden's widow also blames him for the tragedy.